In a large mixing bowl, whisk together the flour, cocoa powder, sugar, baking soda, baking powder, salt, and espresso powder (if using). Set the dry ingredients aside. In a separate bowl, using a handheld mixer or a stand mixer fitted with a whisk attachment (or simply a hand whisk), mix the oil, eggs, and sour cream on medium-high speed until well combined. Add the buttermilk and vanilla extract, and continue beating until fully incorporated. Slowly pour the wet ingredients into the dry ingredients, then add the hot water or coffee. Mix on low speed or gently whisk by hand until the batter is smooth and fully combined. Fold in the mini chocolate chips that have been tossed in flour. The batter will be thin and may have some air bubbles on the surface, which is completely normal. You should have about 6 to 6½ cups of batter (approximately 1400g).