Preheat your oven to 350°F. Cut three 9-inch round parchment paper circles to line the cake pans. Generously spray the sides and bottoms of each pan with nonstick cooking spray, place the parchment circles inside, then spray the parchment again to ensure nothing sticks. Set the pans aside. In a stand mixer fitted with the paddle attachment, or using a handheld mixer in a large bowl, combine both sugars, flour, cocoa powder, baking soda, baking powder, and salt. Mix on low speed until all dry ingredients are thoroughly blended. Break up any large clumps by hand if necessary. In a separate bowl, whisk together the eggs, egg yolks, sour cream, milk, oil, and vanilla extract until fully combined. Pour the wet ingredients into the dry mixture and beat on low until just combined. Add the hot water and mix on low for about one minute until fully incorporated; the batter will be thin. Divide the batter evenly among the prepared pans and bake for about 30 minutes or until a toothpick inserted into the center comes out clean or with a few moist crumbs. Let cakes cool in pans for 10 minutes before transferring to a wire rack to cool completely before frosting.